
XRD data files for this paper were collected between 15/06/2024 and 14/04/2026.  


For structure determination and phase purity data for the 140C treatment were collected between 5 – 120o 2θ on a D8 (Cu Kα). The prisitne and 160C recovered TNO were collected between 10 - 120 o 2θ on a D8 (Cu Kα) and the synthesised lithiated rutile phase was collected between 20 - 100 o 2θ on a D8 (Cu Kα).

7 scans of 44 minutes in length were done for the recovered TNO at 140C on 18/09/2025 on a STOE STADI P diffractometer between 2–90° 2θ (Mo Kα1) using a spinning capillary setup.

For the DIAD experiments 18 XRDs were collected for 18 different spots and the XRD files are shown in the DIAD patterns folder