Research data supporting 'X-ray pair distribution function analysis, electrical and electrochemical properties of cerium doped Li5La3Nb2O12 garnet solid-state electrolyte'

Dong, Bo and Stockham, Mark and Chater, Philip and Slater, Peter (2020) Research data supporting 'X-ray pair distribution function analysis, electrical and electrochemical properties of cerium doped Li5La3Nb2O12 garnet solid-state electrolyte'.

Dataset Details

Data creator(s):

Creators	Email	ORCID
Dong, Bo	B.Dong@bham.ac.uk	orcid.org/0000-0003-0964-5852
Stockham, Mark	MPS846@student.bham.ac.uk	UNSPECIFIED
Chater, Philip	philip.chater@diamond.ac.uk	UNSPECIFIED
Slater, Peter	p.r.slater@bham.ac.uk	orcid.org/0000-0002-6280-7673

Research Data Type:

Dataset

DOI:

https://doi.org/10.25500/edata.bham.00000532

Publisher:

University of Birmingham

Funder:

Engineering and Physical Sciences Research Council

Keywords:

X-ray Pair Distribution Function; Garnet Solid-State Electrolyte; Cerium Doping

Managing organisational unit:

Colleges (2008 onwards) > College of Engineering & Physical Sciences

UoB School, Department or Institute:

School of Chemistry

Date:

10 August 2020

Additional Details

Project/Grant:

EP/R024006/1: ICSF Wave 1: GENESIS: Garnet Electrolytes for New Energy Storage Integrated Solutions, APC (GEM: Garnet Electrolyte Manufacture 56065).

Primary language:

English

Collection period:

From	To
1 March 2019	15 July 2020

Data collection method:

A Bruker D8 X-ray diffractometer (XRD) with a CuKα radiation and linear position sensitive detector was used to collect X-ray diffraction data. Patterns were recorded over the 2θ range 15° to 80° with a 0.02° step size. Structural refinement was carried out with the GSAS suite of Rietveld refinement software using the XRD data. Total scattering data were collected at the I15-1 XPDF beamline at Diamond Light Source, UK. Powdered samples were loaded into borosilicate capillaries (1.5 mm OD, 1.17 mm ID) and spun perpendicular to the beam during data collection to improve powder averaging. Scattering data were collected at an X-ray energy of 76.69 keV using a Perkin Elmer XRD 4343 CT area detector placed ~200 mm from the sample. The 2-D data were corrected for polarization and flat-field, then integrated to 1-D using the DAWN package prior to processed the scattering range 0.7 Å−1 ≤ Q ≤ 25 Å−1 into PDFs using the GudrunX package. A modified Lorch Function (∆1 = 0.05 Å) was applied to suppress spurious low-r features.

Depositing User:

Bo Dong

Date Deposited:

11 Aug 2020 10:16

Last Modified:

11 Aug 2020 10:25

Available Files

Data

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