Experiment FL 38b,130.99°C at t = 0,min = 126.09°C,Ret time 5.501,PLA grade 2500HP,,NMR,NMR,NMR,,,Experiment FL 38a,128.65°C at t = 0,min = 123.43°C,Ret time 5.501,PLA grade 2500HP,,NMR,NMR,NMR,,,Zinc (1),,,,,,,,,,,,,,,,,,,,, Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of butyl lactate ,Time (m),INT (PLA),CE (Oligomer),Bt-La,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of butyl lactate ,Time (m),INT (PLA),CE (Oligomer),Bt-La,,,Butanol,Temp (K),k1,±,k2,±,k-2,±,,ln(k),1/T,,ln(k2),1/T,,ln(k-2),1/T,,,Ea J/mol,Ea kJ/mol,butanol 0,130.99,7.2,0,0,0,100,0,0,0.017006801,,0,128.65,5.7,0,0,0,100,0,0,0.012084896,130,FL 38b,403.15,0.017006801,0.000996717,0.007221105,0.000590029,0.000963834,0.000403766,,-4.074141958,0.002480466,,-4.930747346,0.002480466,,-6.944591939,0.002480466,,k1,51912.57,51.91257, 10,130.22,7.2,77.7,0.002136082,10,81,17,2,0.007221105,,10,124.5,5.7,52.26,0.001436701,10,94,6,0,0.00687903,110,FL 12f,383.15,0.011149102,0.001076237,0.006130624,0.00095408,0.00115554,0.000568127,,-4.496396309,0.002609944,,-5.094458804,0.002609944,,-6.763187866,0.002609944,,k2,58469.16,58.46916, 30,130.36,7,331.75,0.009120275,30,58,35,7,0.000963834,,20,127.73,5.7,128.35,0.003528522,20,77,20,3,0.001427475,90,FL 11d,363.15,0.003126328,0.000512428,0.001083388,0.000312257,0.000439477,0.000201466,,-5.767896231,0.002753683,,-6.827661911,0.002753683,,-7.729924045,0.002753683,,k-2,24464.64,24.46464, 60,129.92,6.9,735.06,0.020207835,60,34,48,18,,,30,128.81,5.4,289.37,0.007955189,30,68,23,9,,,,,,,,,,,,,,,,,,,,,,,, 90,129.94,6.6,865.91,0.023805086,90,27,51,22,0.000996717,,45,129.32,5.2,404.89,0.011130997,45,59,32,9,0.000796103,,,,,,,,,,,,,,,,,,,,,,, 120,130,6.1,1457.79,0.040076701,120,9,51,40,0.000590029,,60,129.52,5,507.15,0.013942268,60,48,36,16,0.000799535,,,,,,,,,,,,,,,,,,,,,,, 180,130,6.1,1940.28,0.053341031,180,5,43,52,0.000403766,,90,129.64,4.9,808.09,0.022215533,90,28,50,22,0.000426595,,,,,,,,,,,,,,,,,,,,,,, 240,130,5.9,2388.07,0.065651409,240,2,34,64,,,120,129.93,4.8,991.46,0.027256632,120,25,47,28,,,,,,,,,,,,,,,,,,,,,,,, 300,129.96,5.6,2636.23,0.072473677,300,0,28,72,,,180,130.41,4.7,1414.39,0.038883574,180,10,46,44,,,,,,,,,,,,,,,,,,,,,,,, 600,130,5.3,3422.97,0.094102268,600,0,11,89,,,240,130.35,4.5,1822.29,0.05009732,240,0,38,62,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,340,130.26,4.4,2303.33,0.063321787,340,0,35,65,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,470,130.22,4.3,2663.29,0.073217595,470,0,25,75,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,690,130.9,4.1,2903.03,0.079808385,690,0,18,82,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,1524,131.31,4.1,3433.39,0.094388729,1524,0,12,88,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Experiment FL 12f,110.64°C at t = 0,min = 106.31°C,Ret time 5.531,PLA grade 6202D,,NMR,NMR,NMR,,,Experiment FL 12b,110.08°C at t = 0,min = 107.57°C,Ret time 5.501,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,, Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of butyl lactate ,Time (m),INT (PLA),CE (Oligomer),Bt-La,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of butyl lactate ,Time (m),INT (PLA),CE (Oligomer),Bt-La,,,,,,,,,,,,,,,,,,,,,,,, 0,110.64,5.7,0,0,0,100,0,0,0.011149102,,0,110.08,3.1,0,0,0,100,0,0,0.007038488,,,,,,,,,,,,,,,,,,,,,,, 10,111.37,5.7,interferance,0,10,87,11,2,0.006130624,,10,112.34,3.1,15.6,0.001,10,92,8,0,0.002976629,,,,,,,,,,,,,,,,,,,,,,, 30,110.37,5.1,274.2,0.007538144,30,74,21,5,0.00115554,,30,110.12,3,143.76,0.004,30,71,25,4,0.00100637,,,,,,,,,,,,,,,,,,,,,,, 60,110.02,4.8,602.73,0.016569897,60,50,36,14,,,60,110.07,2.9,314.88,0.013,60,57,35,8,,,,,,,,,,,,,,,,,,,,,,,, 90,110,4.6,928.66,0.025530172,90,27,49,24,0.001076237,,120,110,2.9,570.27,0.023,120,43,43,14,0.001040156,,,,,,,,,,,,,,,,,,,,,,, 120,109.96,4.3,1160.68,0.031908729,120,21,48,31,0.00095408,,180,110,2.9,781.99,0.031,180,30,48,22,0.000918014,,,,,,,,,,,,,,,,,,,,,,, 180,109.98,4.1,1525.13,0.041927973,180,18,41,41,0.000568127,,360,110,2.9,873.04,0.035,360,19,48,33,0.000427277,,,,,,,,,,,,,,,,,,,,,,, 240,110,4,1824.85,0.050167698,240,13,41,47,,,1260,110,2.7,1423.89,0.056,1260,2,33,65,adjusted,,,,,,,,,,,,,,,,,,,,,,, 335,110,3.9,2170.93,0.059681924,335,8,34,58,,,1926,110,2.5,2601.58,0.098,1926,1,30,69,adjusted,,,,,,,,,,,,,,,,,,,,,,, 545,110,3.6,2790.97,0.076727698,545,4,19,77,,,,,,,Pseudo data based off averages ,2900,0,26,74,,,,,,,,,,,,,,,,,,,,,,,, 1143,110.01,3.5,3496.49,0.096123436,1143,0,12,88,,,,,,,,4500,0,12,88,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Experiment FL 11d,90.05°C at t = 0,min = 86.89°C,Ret time 5.501,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of butyl lactate ,Time (m),INT (PLA),CE (Oligomer),Bt-La,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 0,90.05,2.6,0,0,0,100,0,0,0.003126328,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 20,90.42,2.6,66.61,0.001732064,20,89,10,1,0.001083388,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 60,90,2.5,113.33,0.002946928,60,75,22,3,0.000439477,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 120,90,2.4,307.41,0.007993603,120,60,33,7,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 240,90,2.2,532.23,0.013839613,240,43,43,14,0.000512428,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 576,90,2.1,1105.53,0.028747172,576,25,48,27,0.000312257,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 1188,90,2,1689.25,0.043925683,1188,15,42,43,0.000201466,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 1968,90,1.9,2046,0.053202278,1968,5,40,55,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 2862,89.81,1.8,2372.89,0.061702421,2862,3,34,63,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 4692,90,2,2700.78,0.070228567,4692,1,27,72,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 7548,90,8,3078.78,0.080057727,7548,1,21,78,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,