Experiment FL 4a,54.25°C at t = 0,min = °C,Ret time 5.113,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,Zinc (1),,,,,,,,,,,,,,,,,,,,,,,,,4%
Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of eythl lactate ,Time (m),INT (PLA),CE (Oligomer),Et-La,,,,,,,,,,,ethanol ,Temp (K),k1,±,k2,±,k-2,±,,ln(k),1/T,,ln(k2),1/T,,ln(k-2),1/T,,,Ea J/mol,Ea kJ/mol,ethanol,,,Ea kJ/mol,methanol
0,54.25,0.7,0,0,0,100,0,0,,,,,,,,,,110, FL 3a,383.15,0.039203818,0.003432888,0.016250516,0.002051064,0.002097499,0.00087411,,-3.238981144,0.002609944,,-4.119630599,0.002609944,,-6.167009761,0.002609944,,k1,62582.61,62.58261,,,k1,37.9,
30,50.71,0.6,0,0,30,92,8,0,,,,,,,,,,90, FL 15a,363.15,0.01711605,0.000795591,0.008709775,0.000532533,0.000702873,0.000242193,,-4.067738673,0.002753683,,-4.743309373,0.002753683,,-7.260334421,0.002753683,,k2,55610.52,55.61052,,,k2,39.6,
60,49.99,0.6,1.58,0.001,60,92,8,0,,,,,,,,,,70, FL 14b,343.15,0.005088759,0.000410306,0.002289182,0.000298518,0.00030417,0.000169024,,-5.280721271,0.002914177,,-6.079560895,0.002914177,,-8.09792224,0.002914177,,k-2,54114.72,54.11472,,,k-2,37.2,
120,50,0.6,3.32,0.001,120,84,15,1,,,,,,,,,,50, FL 4a,323.15,0.001039621,0.000572403,0.00070036,0.000814748,8.32861E-05,0.000569997,,-6.868898579,0.003094538,,-7.263916105,0.003094538,,-9.393228637,0.003094538,,,,,,,,,
180,50,1,10.02,0.002,180,80,18,2,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,Ea J/mol,Ea kJ/mol,propanol,,,,8%
360,50,1,21.57,0.004,360,68,27,6,,,,,,,,,,,,,,,,,,,,,,,,,,,,,k1,35300.88,35.30088,,,,Ea kJ/mol,methanol
600,50,0.8,43.06,0.007,600,55,36,8,,,,,,,,,,,,,,,,,,,,,,,,,,,,,k2,32550.27,32.55027,,,k1,40.8,
1080,50,0.7,99.65,0.018,1080,33,43,23,,,,,,,,,,,,,,,,,,,,,,,,,,,,,k-2,20384.43,20.38443,,,k2,44.7,
1620,50,0.7,156.75,0.028,1620,21,43,36,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,k-2,40.8,
2550,50,0.7,239.85,0.043,2550,8,36,56,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,Ea J/mol,Ea kJ/mol,butanol,,,,
3270,50,0.9,293.18,0.053,3270,1,23,76,,,,,,,,,,,,,,,,,,,,,,,,,,,,,k1,51912.57,51.91257,,,,,
4650,50,1,355.05,0.064,4650,0,19,81,,,,,,,,,,,,,,,,,,,,,,,,,,,,,k2,58469.16,58.46916,,,,,
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Experiment FL 14b,70.05°C at t = 0,min = 68°C,Ret time 5.113,PLA grade 2500HP,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of eythl lactate ,Time (m),INT (PLA),CE (Oligomer),Et-La,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
0,70.05,1,0,0,0,100,0,0,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
20,70.07,1.1,6.48,0.002,20,77,20,2,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
40,69.99,1,12.67,0.003,40,73,24,3,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
60,70.01,1,20.31,0.004,60,68,28,4,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
120,70,1,45.45,0.008,120,52,38,9,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
180,70,1,71.61,0.013,180,41,44,15,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
240,70,1,98.57,0.018,240,31,48,21,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
300,70,1,125.85,0.023,300,24,49,28,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
420,70,1,175.93,0.032,420,15,47,38,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
600,70,1,237.95,0.043,600,9,41,50,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
840,70.01,1,302.68,0.055,840,5,31,65,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
1140,70.01,1,349.34,0.063,1140,2,22,76,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
1500,70,0.9,382.5,0.069,1500,0,16,84,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
1920,70,0.9,407.77,0.074,1920,0,9,91,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
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Experiment FL 15a,90.06°C at t = 0,min = 87.11°C,Ret time 5.113,PLA grade 2500HP,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of eythl lactate ,Time (m),INT (PLA),CE (Oligomer),Et-La,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
0,90.06,1.8,0,0,0,100,0,0,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
10,91.7,1.7,7.51,0.002,10,83,16,1,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
20,90.35,1.8,24.29,0.004,20,69,27,4,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
40,90.04,1.9,56.01,0.01,40,46,41,13,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
60,90.01,1.8,82.61,0.015,60,35,46,19,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
90,89.95,1.9,126.96,0.023,90,23,46,31,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
120,90,1.8,169.41,0.031,120,13,45,42,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
150,90,1.7,211.2,0.038,150,10,39,51,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
180,89.99,1.6,243.5,0.044,180,6,36,58,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
240,90.01,1.8,292.33,0.053,240,0,30,70,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
300,90,1.7,324.97,0.059,300,0,21,79,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
360,90,1.7,349.81,0.063,360,0,18,82,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
420,90,1.7,367.7,0.066,420,0,8,92,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
480,90,1.8,383.82,0.069,480,0,8,92,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
540,90,1.8,389.7,0.071,540,0,7,93,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
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Experiment FL 3a,110.02°C at t = 0,min = 109.02°C,Ret time 5.113,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of eythl lactate ,Time (m),INT (PLA),CE (Oligomer),Et-La,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
0,110.02,3,0,0,0,100,0,0,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
5,112.98,2.9,0,0,5,90,9,1,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
10,114.1,2.8,21,0.001,10,56,37,7,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
15,111.74,2.6,40.56,0.007,15,50,40,10,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
25,109.8,2.6,81.79,0.015,25,38,45,18,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
35,110.04,2.4,116.6,0.021,35,26,50,24,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
45,109.99,2.4,136.72,0.025,45,24,46,30,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
60,109.99,2.5,204.67,0.037,60,12,46,42,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
80,110,2.4,242.06,0.044,80,10,39,51,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
130,110,2.2,319.39,0.058,130,0,31,69,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
160,110.01,2.2,350.95,0.063,160,0,23,77,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
190,109.97,2.1,376.56,0.068,190,0,19,81,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
240,109.99,2,397.92,0.072,240,0,14,86,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
300,110.01,2,420.47,0.076,300,0,9,91,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
360,110.06,2.2,430.74,0.078,360,0,8,92,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
420,108.73,2,442.33,0.08,420,0,4,96,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,