Experiment FL5a,110.71°C at t = 0,min = 108.83°C,Ret time 5.35,PLA grade 6202D,,NMR,NMR,NMR,,,,,Experiment FL5b,110.48°C at t0,tmin = 108.61°C,Ret time 5.35,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,Zinc (1),,,,,,,,,,,,,,,,,,,,, Time (m),Temperture (°C),Pressure (bar),Peak area ,,Time (m),INT (PLA),CE (Oligomer),Pro-La,,0.013900546,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,,Time (m),INT (PLA),CE (Oligomer),Pro-La,,,,,,,,,,,,,Propanol,Temp (K),k1,±,k2,±,k-2,±,,ln(k),1/T,,ln(k2),1/T,,ln(k-2),1/T,,,Ea J/mol,Ea kJ/mol,propanol 0,110.71,3.3,0,,0,100,0,0,,0.004885848,,,0,110.48,3.6,0,,0,100,0,0,0.015567883,,,,,,,,,,,130,FL 37b,403.15,0.019670183,0.000966981,0.008084791,0.000614369,0.000896828,0.000388534,,-3.928651364,0.002480466,,-4.817770683,0.002480466,,-7.01664635,0.002480466,,k1,35300.88,35.30088, 5,108.95,3.3,11.59,,5,91,8,1,,0.000674652,,,10,110.36,3.6,34.98,,10,84,14,2,0.006769619,,,,,,,,,,,110,FL 5a,383.15,0.013900546,0.000861169,0.004885848,0.000452806,0.000674652,0.00033483,,-4.275827177,0.002609944,,-5.321412357,0.002609944,,-7.301313014,0.002609944,,k2,32550.27,32.55027, 10,110.8,3.1,33.47,,10,85,14,1,,,,,20,11.13,3.4,148.47,,20,69,27,4,0.001101939,,,,,,,,,,,90,FL 7b,363.15,0.006203986,0.000620841,0.002772705,0.000507256,0.000459313,0.000204743,,-5.082563243,0.002753683,,-5.887931926,0.002753683,,-7.685777661,0.002753683,,k-2,20384.43,20.38443, 15,110.74,3.1,57.21,,15,79,19,2,,0.000861169,,,40,110.09,3.4,296.12,,40,53,38,9,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 20,110.16,3.2,97.44,,20,72,25,3,,0.000452806,,,60,110.02,3.3,565.79,,60,36,44,20,0.001295966,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 30,109.98,3.2,174.58,,30,63,32,5,,0.00033483,,,90,109.98,3.1,849.59,,90,22,50,28,0.000830944,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 45,110,3.1,311.81,,45,49,41,10,,,,,120,109.97,2.9,1084.99,,120,16,49,35,0.000452771,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 60,110,3.1,417.73,,60,40,46,15,,,,,180,110,28,1406.64,,180,9,45,46,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 90,110,3,639.29,,90,28,50,22,,,,,240,110,2.7,1694.31,,240,6,35,59,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 120,110,3,792.32,,120,21,51,28,,,,,360,110,2.6,2036.99,,360,2,30,68,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 180,110,2.4,1143.14,,180,13,48,39,,,,,600,110,2.4,2524.05,,600,0,19,81,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 240,110,2.4,1419.74,,240,7,45,48,,,,,1320,110,2.3,2982.94,,1354,0,6,94,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 300,110,2.1,1634.15,,300,5,39,56,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 360,110,2.1,1820.14,,360,1,36,63,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 1260,110,2.1,2722.28,,1260,0,9,91,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,Experiment FL 7b,90.40°C at t = 0,min = 87.23°C,Ret time 5.35,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,,Time (m),INT (PLA),CE (Oligomer),Pro-La,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,0,90.4,1.9,0,,0,100,0,0,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,20,90.67,1.9,63.94,,20,83,15,2,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,60,90.13,1.7,211.73,,60,66,29,5,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,90,90.1,1.7,340.84,,90,50,39,11,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,120,87.91,1.6,481.11,,120,43,43,14,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,180,90,1.5,695.03,,180,36,42,22,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,300,90,1.4,1052.31,,300,19,46,35,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,598,90,1.3,1593.45,,598,7,40,53,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,1272,90,0.6,2295.67,,1271,3,21,76,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,2058,90,0.6,2674.52,,2058,0,14,86,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,2796,90,1,2798.64,,2796,0,8,92,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Experiment FL37b,128.27°C at t = 0,min = 123.25°C,Ret time 5.35,PLA grade 6202D,,NMR,NMR,NMR,,0.019670183,,,Experiment FL37c,131°C at t = 0,min = 127.56°C,Ret time 5.35,PLA grade 6202D,,NMR,NMR,NMR,,0.015475154,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Time (m),Temperture (°C),Pressure (bar),Peak area ,,Time (m),INT (PLA),CE (Oligomer),Pro-La,,0.008084791,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,,Time (m),INT (PLA),CE (Oligomer),Pro-La,,0.00779431,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 0,128.27,4.8,0,,0,100,0,0,,0.000896828,,,0,131,6.4,0,,0,100,0,0,,0.000869843,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 5,123.25,4.8,0,,5,89,10,1,,,,,10,130.31,6.4,95.38,,10,82,15,3,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 10,125.57,4.9,55.37,,10,80,18,2,,0.000966981,,,20,130.63,6,151.37,,20,78,18,4,,0.000882581,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 15,1227,4.8,116.15,,15,71,25,4,,0.000614369,,,40,130.01,5.9,358.99,,40,52,38,10,,0.000684419,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 20,127.55,4.8,158.39,,20,65,30,5,,0.000388534,,,60,129.95,5.6,558.36,,60,38,44,18,,0.000407075,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 30,127.58,4.7,275.77,,30,53,38,9,,,,,90,130,5.3,833.5,,90,23,49,28,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 45,127.73,4.4,455.13,,45,40,45,15,,,,,120,130,4.8,1114.07,,120,12,50,38,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 60,128.65,4.3,625.78,,60,30,48,22,,,,,180,130,4.9,1540.65,,180,7,39,53,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 80,129.66,4.2,819.84,,80,21,50,29,,,,,240,130,4.7,1894.03,,240,3,33,64,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 110,129.8,4.2,1056.44,,110,14,48,38,,,,,340,130,4.6,2277.36,,340,1,22,77,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 145,130,4,1393.17,,145,7,51,51,,,,,642,130,4.5,2839.15,,642,0,8,92,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 180,129.79,4,1491.46,,180,4,42,54,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 240,130.2,4,1961.23,,240,2,29,69,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 360,130.14,3.9,2310.56,,360,0,17,83,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 590,130.03,3.9,2636.21,,590,0,8,92,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,