,,,19885,,,,,,,,,,,,,,,19885,,,,,,,,,,,,,19885,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
Experiment E1a,130.14°C at t = 0,min = 127.23°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,(g) - (g),,,,,Experiment E2a,122.14°C at t = 0,min = 117.17°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,Experiment E3a,109.97°C at t = 0,min = 106.45°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,Experiment E4a,100.01°C at t = 0,min = 96.52°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,Temp,#,k1,k2,,,#,K1,T (°C),T (k),1/T,lnk,,,,,,#,K1,T (°C),T (k),1/T,lnk
Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,DMAP - ZnAc,Experiment,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,130,E1a adj,0.0858,0.0274,,,E1a,0.0858,130,403.15,0.002480466,-2.455736272,,,,,,E1a,0.0858,130,403.15,0.002480466,-2.455736272
0,130.14,6.5,0,0,0,100,0,0,,0.05 - 0.05,E1a,,,,0,122.14,5.6,0,0,0,100,0,0,,,,,0,109.97,3.9,0,0,0,100,0,0,,,,,0,100.01,2.9,0,0,,,,,,130,E1c adj,0.0445,0.0275,,,E2a,0.0717,120,393.15,0.002543558,-2.635264531,,,,,,avg (E2a+E2c),0.0548,120,393.15,0.002543558,-2.904065085
5,129.2,6.5,14.79,0.000743777,5,51,41,8,,0.05 - 0.05,E1b,,,,5,122.86,5.6,6.57,0.0003304,5,43,45,12,,,,,10,110.51,3.9,28.22,0.00141916,10,19,48,33,,,,,10,100.48,2.9,31.54,0.00158612,,,,,,120,E2a,0.0717,0.0175,,,E3c,0.0289,110,383.15,0.002609944,-3.543913684,,,,,,E3c,0.0289,110,383.15,0.002609944,-3.543913684
10,132.65,7.1,90,0.004526025,10,35,49,16,,0.05 - 0.05,E2a,,,,11,121.35,5.5,59.74,0.003004275,11,32,50,18,,,,,20,110.24,3.9,161.97,0.008145336,20,14,42,44,,,,,20,100.06,2.9,132.07,0.00664169,,,,,,120,E2c adj,0.0378,0.0203,,,E4e,0.0152,100,373.15,0.002679887,-4.186459851,,,,,,E4e,0.0152,100,373.15,0.002679887,-4.186459851
15,133.88,7.4,205.35,0.01032688,15,27,51,22,,0.05 - 0.05,E2b,,,,20,120.66,5.6,153.86,0.007737491,20,30,49,22,,,,,40,110.04,3.8,413.47,0.02079306,40,10,42,48,,,,,40,100,2.9,261.81,0.013166206,,,,,,110,E3c,0.0289,0.0143,,,,,,,,,,,,,,,,,,,
20,132.18,7.4,289.02,0.014534574,20,22,51,27,,0.05 - 0.05,E3a,,,,40,119.97,5.5,394.42,0.019835052,40,15,49,36,,,,,60,109.98,3.8,602.56,0.030302238,60,4,41,55,,,,,60,100,3,393.62,0.01979482,,,,,,110,E3d adj,0.0224,0.0111,,,,,,,,,,,,,,,,,,,
30,130.45,7.3,512.79,0.02578778,30,10,49,41,,0.05 - 0.05,E3b,,,,60,119.97,5.5,628.25,0.031594166,60,7,42,51,,,,,90,110.04,3.9,838.66,0.042175509,90,,,,,,,,90,100.01,3.2,545.36,0.027425698,,,,,,110,E3e adj,0.0217,0.0122,,,,,,,,,,,,,,,,,,,
40,129.88,7.4,698.05,0.03510435,40,4,44,52,,0.05 - 0.05,E4a,,,,90,119.95,5.6,889.68,0.044741262,90,0,33,67,,,,,120,109.98,3.9,1006.19,0.050600453,120,,,,,,,,120,100,2.9,641.51,0.032261001,,,,,,100,E4d adj,0.0114,0.0079,,,,,,,,,,,,,,,,,,,
50,130,7.4,842.56,0.042371637,50,0,38,62,,0.05 - 0.05,E4b,,,,120,119.98,5.6,1063.62,0.053488559,120,0,21,79,,,,,140,110.04,4.4,1081.81,0.054403319,140,,,,,,,,180,100,3.1,813.71,0.040920795,,,,,,100,E4e adj,0.0152,0.0103,,,,,,,,,,,,,,,,,,,
60,130.05,7.3,967.36,0.048647724,60,0,28,72,,0.05 - 0.05,E4c,,,,140,120,5.8,1148.75,0.057769676,140,0,17,83,,,,,,,,,,,,,,,,,,240,100.02,3,936.09,0.047075182,,,,,,100,E4f adj,0.0138,0.007,,,,,,,,,,,,,,,,,,,
80,130.06,7.4,1116.04,0.056124717,80,0,19,81,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,300,100,3,1014.71,0.051028916,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,#,K1,T (°C),T (k),1/T,lnk,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,Avg,0.0652,130,403.15,0.002480466,-2.73029581,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,Avg,0.0548,120,393.15,0.002543558,-2.904065085,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,Avg,0.0243,110,383.15,0.002609944,-3.717278929,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,Avg,0.0135,100,373.15,0.002679887,-4.305065594,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,#,K1,T (°C),T (k),1/T,lnk,,,,,,#,K2,T (°C),T (k),1/T,lnk
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,E1a,0.0858,130,403.15,0.002480466,-2.455736272,,,,,,E1a,0.0274,130,403.15,0.002480466,-3.597212266
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,E2c,0.0378,120,393.15,0.002543558,-3.275446176,,,,,,avg (E2a+E2c),0.0189,120,393.15,0.002543558,-3.968593357
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,E3c,0.0289,110,383.15,0.002609944,-3.543913684,,,,,,E3c,0.0143,110,383.15,0.002609944,-4.247495742
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,E4e,0.0152,100,373.15,0.002679887,-4.186459851,,,,,,E4e,0.0103,100,373.15,0.002679887,-4.575611384
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,21872,,,,,,,,,,,,,,,19885,,,,,,,,,,,,,19885,,,,,,,,,, 120C for 5min to dissolve PLA,,,21872,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
Experiment E1b,130.48°C at t = 0,min = 125.69°C,Ret time 4.524,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,Experiment E2b,121.28°C at t = 0,min = 119.57°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,Experiment E3b,110.02°C at t = 0,min = 106.34°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,Experiment E4b,99.53°C at t = 0,min = 95.73°C,Ret time 4.533,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,
Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,,,,,,,,,,,,,,,,,,,,
0,130.48,7.1,0,0,,,,,,,,,,,0,121.28,5.5,0,0,,,,,,,,,0,110.02,4,0,0,,,,,,,,,0,99.53,3.1,0,0,,,,,,,,,,,,,,,,,,,,,,,,,,,,
10,132.39,7.1,71.84,0.003284565,,,,,,,,,,,10,122.76,5.5,74.61,0.003752074,,,,,,,,,10,110.79,4,29.18,0.001467438,,,,,,,,,10,100.03,3.1,8.61,0.000393654,,,,,,,,,,,,,,,,,,,,,,,,,,,,
20,131.72,7,396.39,0.018123171,,,,,,,,,,,20,121.04,5.3,455.53,0.022908222,,,,,,,,,20,110.16,3.9,202.31,0.010174001,,,,,,,,,20,99.95,3,34.35,0.001570501,,,,,,,,,,,,,,,,,,,,,,,,,,,,
30,130.5,7,580.84,0.026556328,,,,,,,,,,,30,120.27,5.2,603.77,0.030363088,,,,,,,,,30,110,3.9,321.79,0.01618255,,,,,,,,,40,99.95,3,98.17,0.004488387,,,,,,,,,,,,,,,,,,,,,,,,,,,,
40,129.69,6.8,711.55,0.032532462,,,,,,,,,,,40,120.11,5.2,709.61,0.035685693,,,,,,,,,40,110,3.9,428.09,0.021528288,,,,,,,,,60,99.95,3,166.74,0.007623446,,,,,,,,,,,,,,,,,,,,,,,,,,,,
50,130.2,7,864.41,0.039521306,,,,,,,,,,,50,120,58.2,803.14,0.040389238,,,,,,,,,60,110,3.9,598.84,0.030115162,,,,,,,,,90,100,3,288.37,0.013184437,,,,,,,,,,,,,,,,,,,,,,,,,,,,
60,129.98,6.9,930.29,0.042533376,,,,,,,,,,,60,120.11,5.3,884.04,0.044457631,,,,,,,,,80,110,4,775.4,0.038994217,,,,,,,,,120,100,3.2,412.38,0.018854243,,,,,,,,,,,,,,,,,,,,,,,,,,,,
80,129.98,7,1079.54,0.049357169,,,,,,,,,,,90,119.98,5.4,1021.27,0.051358813,,,,,,,,,110,110.02,4.1,945.39,0.047542872,,,,,,,,,180,100,3.1,559.07,0.025560991,,,,,,,,,,,,#,K1,T (°C),T (k),1/T,lnk,,,,,,#,K1,T (°C),T (k),1/T,lnk
,,,,,,,,,,,,,,,120,119.98,5.5,1117.37,0.056191602,,,,,,,,,140,110.02,4,1010.87,0.050835806,,,,,,,,,240,100,3.1,702.87,0.032135607,,,,,,,,,,,,E1a,0.0858,130,403.15,0.002480466,-2.455736272,,,,,,E1a,0.0274,130,403.15,0.002480466,-3.597212266
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,270,100,3,900.66,0.041178676,,,,,,,,,,,,E2c,0.0378,120,393.15,0.002543558,-3.275446176,,,,,,E2c,0.0203,120,393.15,0.002543558,-3.897134393
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,E3e,0.0217,110,383.15,0.002609944,-3.830443018,,,,,,E3e,0.0122,110,383.15,0.002609944,-4.406319327
,,,22230,,,,,,,,,,,,,,,22230,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,E4d,0.0114,100,373.15,0.002679887,-4.474141924,,,,,,E4d,0.0079,100,373.15,0.002679887,-4.84089252
Experiment E1c,130.40°C at t = 0,min = 125.86°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,Experiment E2c,120.42°C at t = 0,min = 114.1°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,21872,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,Experiment E3c,108.69°C at t = 0,min = 105.27°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,, 120C for 5min to dissolve PLA,,,21872,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
0,130.4,7.2,0,0,0,100,0,0,,,,,,,0,120.42,5.2,0,0,0,100,0,0,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,Experiment E4c,100°C at t = 0,min = 95.84°C,Ret time 4.533,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,
10,132.32,7.2,48.93,0.00220108,10,72,22,6,,,,,,,10,120.75,5.2,43.62,0.001962213,10,77,19,4,,,,,0,108.69,3.9,0,0,0,100,0,0,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,,,,,,,,,,,,,,,,,,,,
20,131.33,6.9,383.67,0.017259109,20,29,45,26,,,,,,,20,120.66,5.2,259.29,0.011663968,20,39,43,18,,,,,10,110.38,3.9,15.63,0.000714612,10,64,23,13,,,,,0,100,3.1,0,0,,,,,,,,,,,,,,,,,,,,,,,,,,,,
30,130.45,6.9,588.96,0.026493927,30,15,45,40,,,,,,,30,119.97,5.1,438.46,0.019723797,30,21,48,31,,,,,20,110.31,3.9,172.63,0.00789274,20,37,44,19,,,,,15,99.85,3.1,14.36,0.000656547,,,,,,,,,,,,,,,,,,,,,,,,,,,,
40,130.54,7,747.89,0.033643275,40,7,42,51,,,,,,,40,119.8,5.1,586.86,0.02639946,40,12,48,40,,,,,40,110.02,3.9,384.93,0.017599214,40,20,47,33,,,,,30,99.86,3.1,81.16,0.00371068,,,,,,,,,,,,,,,,,,,,,,,,,,,,
60,129.86,6.9,983.44,0.044239316,60,1,32,67,,,,,,,60,119.98,5.2,840.45,0.037807018,60,3,41,56,,,,,60,109.95,4,582.95,0.026652798,60,10,45,45,,,,,60,100.03,3.1,226.06,0.010335589,,,,,,,,,,,,,,,,,,,,,,,,,,,,
80,130.09,7.1,1141.77,0.051361673,80,0,21,79,,,,,,,90,120.2,5.3,1040.81,0.046820063,90,0,26,74,,,,,90,109.99,3.9,808.99,0.036987473,90,3,37,60,,,,,90,99.96,3.1,345.17,0.015781364,,,,,,,,,,,,,,,,,,,,,,,,,,,,
120,130,6.9,1274.99,0.057354476,120,0,11,89,,,,,,,120,120.11,5.4,1229.71,0.055317589,120,0,19,83,,,,,120,110.02,4.1,950.03,0.0434359,120,0,31,69,,,,,120,99.96,3.1,527.44,0.02411485,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,180,110.01,4.1,1213.98,0.055503841,180,0,20,82,,,,,150,99.97,3.2,678.63,0.031027341,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,180,99.96,3.3,768.34,0.035128932,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,240,99.97,3.4,984.85,0.04502789,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,300,99.98,3.3,1044.94,0.047775238,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,Experiment E3d,112.01°C at t = 0,min = 105.99°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,0,112.01,3.9,0,0,0,100,0,0,,,,,,,,22230,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,20,110.15,3.9,42.07,0.001892488,20,70,23,7,,,,,Experiment E4d,100.08°C at t = 0,min = 96.19°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,40,110,3.9,312.32,0.014049483,40,24,49,27,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,60,110.07,4,487.54,0.021931624,60,13,49,38,,,,,0,100.08,2.9,0,0,0,100,0,0,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,90,110.04,4,657.51,0.029577598,90,4,44,52,,,,,30,100.03,2.9,56.47,0.002540261,30,73,22,5,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,120,109.95,4,796.19,0.035816014,120,0,38,62,,,,,60,100.49,2.9,324.44,0.014594692,60,30,45,25,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,180,110,4.1,1028.66,0.046273504,180,0,25,76,,,,,90,100.04,3,476.28,0.021425101,90,23,41,36,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,240,109.99,4.1,1086.93,0.048894737,240,0,15,85,,,,,120,99.72,3.1,570.4,0.025659019,120,16,41,43,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,180,100,3.1,787.49,0.035424651,180,8,31,61,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,300,99.98,3.2,998.16,0.044901484,300,1,24,75,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,420,100.01,3.1,1064.15,0.047869996,420,0,13,87,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,5 days later,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,Experiment E3e,110.70°C at t = 0,min = 104.77°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,0,110.7,3.9,0,0,0,100,0,0,,,,,,,,22230,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,20,110.43,3.9,72.32,0.003253261,20,62,28,10,,,,,Experiment E4e,100.0°C at t = 0,min = 96°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,40,109.92,3.9,378.06,0.017006748,40,19,49,32, ,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,60,109.96,3.9,558.45,0.025121457,60,7,48,45,,,,,0,100,2.9,0,0,0,100,0,0,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,90,109.99,3.8,746.81,0.033594692,90,1,40,59,,,,,30,100,2.9,85.46,0.003844354,30,56,30,14,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,120,109.95,3.9,879.29,0.039554206,120,0,34,66,,,,,60,100.03,2.9,512.7,0.023063428,60,10,47,43,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,180,109.99,4,1012.8,0.045560054,180,0,19,81,,,,,90,99.96,2.9,673.75,0.030308142,90,3,41,56,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,240,110,4,1157.74,0.052080072,240,0,16,84,,,,,120,99.98,2.9,799.6,0.035969411,120,1,36,64,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,180,100,2.9,885.82,0.039847953,180,0,29,71,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,240,100,2.9,977.62,0.043977508,240,0,22,78,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,360,100.02,2.9,1105.38,0.049724696,360,0,6,94,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,420,100,2.9,1068.55,0.048067926,420,0,9,91,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,Experiment E4f,100.0°C at t = 0,min = 96.1°C,Ret time 4.457,PLA grade 6202D,,NMR,NMR,NMR,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,Time (m),Temperture (°C),Pressure (bar),Peak area ,Concentration of methyl lactate ,Time (m),INT (PLA),CE (Oligomer),Me-La,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,0,100,3,0,0,0,100,0,0,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,30,100.06,3,76.25,0.003430049,30,59,31,10,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,60,100,3,325.66,0.014649573,60,23,49,28,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,90,99.98,3,464.48,0.020894287,90,12,49,39,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,120,99.98,3.1,578.63,0.02602924,120,6,46,48,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,180,100,3,740.72,0.033320738,180,4,34,62,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,240,100,3.1,870.35,0.039152047,240,0,30,70,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,330,99.94,3.2,1027.47,0.046219973,330,0,21,79,,,,,,,,,,,,,,,,,,,,,,,,
,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,420,100,3.2,1044.76,0.046997751,420,0,17,83,,,,,,,,,,,,,,,,,,,,,,,,